Microscopic Structure of NaCd Compound Forming Binary Molten Alloys | Zendy

Sujeet Kumar Chatterjee | Zendy; L. C. Prasad | Zendy; Ajaya Bhattarai | Zendy

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Microscopic Structure of NaCd Compound Forming Binary Molten Alloys

Author(s) -

Sujeet Kumar Chatterjee,

L. C. Prasad,

Ajaya Bhattarai

Publication year - 2011

Publication title -

materials sciences and applications

Language(s) - English

Resource type - Journals

eISSN - 2153-1188

pISSN - 2153-117X

DOI - 10.4236/msa.2011.26081

Subject(s) - materials science , alloy , asymmetry , binary number , thermodynamics , short range order , crystallography , metallurgy , chemistry , physics , arithmetic , mathematics , quantum mechanics

A simple statistical mechanical theory based on compound formation model (compound A_μ B_v formed by the preferential arrangement of A and B constituent atoms of the alloy AB, μA + νB ≒ A_μ B_v) has been used to investigate the phenomena of compound formation in NaCd liquid alloys through the study of concentration fluctuation in the long wavelength region [S_cc(0)] and chemical short range order parameter (α₁). The study explains the observed asymmetry successfully and suggest the existence of Cd₂Na complex in the melt. The tendency of compound has been found to be weak. A tendency of inversion from segregation to order although very small, has been observed, in NaCd liquid alloys

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