Ni Dispersed on Sulfated Zirconia Pillared Montmorillonite as Bifunctional Catalyst in Eco-Friendly Citronellal Conversion | Zendy

Is Fatimah | Zendy; Dwiarso Rubiyanto | Zendy; Thorikul Huda | Zendy; Sri Handayani | Zendy; Oryza Mutiara Ilahi | Zendy; Septian Perwira Yudha | Zendy

Open Access

Ni Dispersed on Sulfated Zirconia Pillared Montmorillonite as Bifunctional Catalyst in Eco-Friendly Citronellal Conversion

Author(s) -

Is Fatimah,

Dwiarso Rubiyanto,

Thorikul Huda,

Sri Handayani,

Oryza Mutiara Ilahi,

Septian Perwira Yudha

Publication year - 2015

Publication title -

engineering journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.246

H-Index - 20

ISSN - 0125-8281

DOI - 10.4186/ej.2015.19.5.43

Subject(s) - bifunctional , citronellal , montmorillonite , cubic zirconia , environmentally friendly , catalysis , materials science , bifunctional catalyst , sulfation , chemical engineering , chemistry , composite material , organic chemistry , engineering , ceramic , biochemistry , ecology , biology

Nickel dispersed on sulfated zirconia pillared montmorillonite was prepared by three main steps; zirconia pillarization, sulfation and nickel dispersion. The synthesized material was characterized with FTIR spectroscopy, elemental analysis, x-ray diffraction and gas sorption analyzer before was tested for microwave assisted citronellal conversion via catalytic hydrogen transfer mechanism. The results showed that the obtained material gave high total conversion and demonstrated cyclization, isomerization and hydrogenation mechanism in one pot reaction. The presence of sulfate and nickel in the catalyst play important role within the mechanism.

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