Mathematical Modeling of Induction Period of the Olefins Hydroalumination Reaction by Diisobutylaluminiumchloride Catalyzed with Cp2ZrCl2 | Zendy

Irek Gubaydullin | Zendy; К. Ф. Коледина | Zendy; Leniza Sayfullina | Zendy

Open Access

Mathematical Modeling of Induction Period of the Olefins Hydroalumination Reaction by Diisobutylaluminiumchloride Catalyzed with Cp2ZrCl2

Author(s) -

Irek Gubaydullin,

К. Ф. Коледина,

Leniza Sayfullina

Publication year - 2014

Publication title -

engineering journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.246

H-Index - 20

ISSN - 0125-8281

DOI - 10.4186/ej.2014.18.1.13

Subject(s) - induction period , asymmetric induction , chemistry , catalysis , period (music) , organic chemistry , physics , acoustics , enantioselective synthesis

Method of mathematical modeling of induction period for reaction of olefins hydroalumination by alkylalanes in presence Cp 2 ZrCl 2 was developed. The kinetic model of reaction of olefins hydroalumination by alkylalanes with presence the catalyst Cp 2 ZrCl 2 was built. The values of kinetic parameters of reaction of olefins hydroalumination by alkylalanes in presence Cp 2 ZrCl 2 which describes well an experimental data were determined. Obtained values are allowed to describe an induction period in all experimentally investigated area. The stages of mechanism of reaction of olefins hydroalumination by alkylalanes in presence Cp 2 ZrCl 2 which determine an existence of induction period were found. The software of mathematical modeling of induction period which allows to define stages determined an existence of induction period was developed. It can be used for wide class of investigated reactions.

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