Cysteine Duality Effect on the Corrosion Inhibition and Acceleration of 3003 Aluminium Alloy in a 2% NaCl Solution
Author(s) -
Brahim El Ibrahimi,
Aaziz Jmiai,
A Somoue,
Rachid Oukhrib
Publication year - 2018
Publication title -
portugaliae electrochimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.252
H-Index - 27
eISSN - 1647-1571
pISSN - 0872-1904
DOI - 10.4152/pea.201806403
Subject(s) - aluminium , alloy , corrosion , cysteine , duality (order theory) , acceleration , materials science , metallurgy , aluminium alloy , chemistry , biochemistry , mathematics , physics , classical mechanics , enzyme , pure mathematics
Cysteine’s action on 3003 aluminum alloy dissolution in a 2% NaCl solution, at different pH values, has been investigated. Weight-loss measurements, potentiodynamic polarization and electrochemical impedance at OCP were performed. The surface morphology was analyzed by SEM. The main results showed that the alloy underwent severe corrosion at 2 and 11 pH values, as compared to at 5 and 8 pH values. Furthermore, a duality effect of cysteine was noted, as it acted as a corrosion inhibitor or accelerator, depending on its concentration, and on the solution’s pH value. This particular behavior can be related to the instability of the formed film adsorbed onto the metal surface. All these findings show the high complexity of cysteine action on 3003 aluminum alloy, under the investigated conditions.
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