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Electropolishing of Metallic Surfaces and the Factors Influencing on the Limiting Current
Author(s) -
A-M M Ahmed,
Mervette Batouti,
S M S Khelil
Publication year - 2015
Publication title -
portugaliae electrochimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.252
H-Index - 27
eISSN - 1647-1571
pISSN - 0872-1904
DOI - 10.4152/pea.201502105
Subject(s) - electropolishing , limiting current , limiting , current (fluid) , materials science , metal , current limiting , metallurgy , chemistry , mechanical engineering , physics , engineering , thermodynamics , electrochemistry , electrode , electrolyte
Anodic limiting currents were measured in an unstirred divided cell at an inclined small scale anode using a large scale cathode with angles of inclination from vertical axis as 45, 60 and 75°. Anode heights (II) vary from 1 cm to 6 cm and phosphoric acid concentration from 6 to 10 moles. Limiting currents for electropolishing of copper were between 5 and 58 mA.cm -2 depending on the operating conditions. A general correlation of data of all inclinations was obtained using the equation: I = 28.57( 0.520 .C -0.89 .H -0.91 ) (1) with an average deviation of ±4%.

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