Inhibition Effects on the Corrosion of Mild Steel in 1 M HCl by 1,1'-(2,2'-(2,2'-oxybis(ethane-2,1-diyl)bis(sulfanediyl)) bis(ethane-2,1-diyl))diazepan-2-one
Author(s) -
Abdelhamid Khadiri,
A. Ousslim,
K. Bekkouche,
A. Aouniti,
A. Elidrissi,
B. Hammouti
Publication year - 2014
Publication title -
portugaliae electrochimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.252
H-Index - 27
eISSN - 1647-1571
pISSN - 0872-1904
DOI - 10.4152/pea.201401035
Subject(s) - corrosion , chemistry , medicinal chemistry , materials science , nuclear chemistry , organic chemistry
The inhibition of the corrosion of Mild Steel (MS) in 1 M HCl solution by a new synthesised organic compound, namely 1,1'-(2,2'-(2,2'-oxybis(ethane-2,1-diyl)bis (sulfanediyl))bis(ethane-2,1-diyl))diazepan-2-one, has been studied by weight loss measurements, electrochemical polarisation and electrochemical impedance spectroscopy (EIS). The experimental results have showed that this organic compound revealed a good corrosion inhibition and the inhibition efficiency is increased with the inhibitor concentration to reach 97% at 1 mM. Potentiodynamic polarisation suggested that it is a mixed type of inhibitor. EIS measurements show an increase of the polarisation resistance with the inhibitor concentration and the electrical equivalent circuit is determined. The inhibitor adsorption process on (MS) surfaces obeys the Langmuir adsorption isotherm and the adsorption isotherm parameters (K ads , Gads ,
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