Properties of Sulfolane Based Aprotic Electrolytes
Author(s) -
Josef Máca,
Martin Frk,
Zdenka Rozsivalova,
Marie Sedlařı́ková
Publication year - 2013
Publication title -
portugaliae electrochimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.252
H-Index - 27
eISSN - 1647-1571
pISSN - 0872-1904
DOI - 10.4152/pea.201306321
Subject(s) - sulfolane , electrolyte , materials science , chemistry , organic chemistry , electrode , solvent
The article deals with description of rheological and electrical properties of solvents for electrolytes of lithium-ion batteries. Solvents mixture of dimethyl sulfone and sulfolane at different volume ratios and with a lithium salt (LiClO 4) appears as a potentially suitable electrolyte. In this work, we investigate the influence of different solvents and their mixtures in order to find a solvent which increases the fire safety of such battery. The aim of this experiment is to investigate the rheological properties, particularly density and dynamic viscosity of solvents with lithium salt in temperature dependence and to find the optimal composition of the electrolyte from the perspective of achieving the lowest dynamic viscosity and better electrical conductivity, because both quantities are closely related with Walden’s rule. The vibration method is used to determine the values of dynamic viscosity.
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