Electrocoagulation and Anodic Oxidation as a Complement of Biological Treatment of Sanitary Landfill Leachates

The electrochemical treatment of leachate samples collected in a Portuguese intermunicipal sanitary landfill was carried out using combined electrocoagulation followed by anodic oxidation processes. Samples were collected after the biological treatment of the in situ plant and in permeate of an ultrafiltration operation, located after the biological treatment. Electrocoagulation was performed with iron consumable anodes, at different initial pH, with and without stirring, at different applied potentials. In the anodic oxidation assays a boron-doped diamond anode was used and applied current densities from 100 to 300 A m -2 were tested. The influence of the experimental conditions of the electrocoagulation pretreatment on the anodic oxidation performance was also assessed. In the electrocoagulation assays the lowest iron and energy consumptions per mass of organic load removed were obtained at initial pH of 4 for the samples collected after the biological treatment and at initial pH of 6 for the sample collected in the ultrafiltration permeate, all in the unstirred assays. In the anodic oxidation, the highest average current efficiencies were obtained in the assays run at lower current density, being higher for the samples collected after the biological treatment. For both type of samples, the correction of the pH prior to the electrocoagulation pretreatment led to a decrease in the average current efficiency during the anodic oxidation.