Corrosion Inhibition by an Aqueous Extract of Phyllanthus Amarus
Author(s) -
M. Sangeetha,
S. Rajendran,
J. Sathiyabama,
A. Krishnaveni,
P. Shanthy,
Nithil Harris Manimaran,
B. Shyamaladevi
Publication year - 2011
Publication title -
portugaliae electrochimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.252
H-Index - 27
eISSN - 1647-1571
pISSN - 0872-1904
DOI - 10.4152/pea.201106429
Subject(s) - aqueous solution , phyllanthus , corrosion , aqueous extract , chemistry , materials science , metallurgy , traditional medicine , medicine , organic chemistry
The inhibition efficiency (IE) of phyllanthus amarus extract (PAE)-Zn 2+ system, in controlling corrosion of carbon steel in an aqueous solution containing 60 ppm of Cl - , has been evaluated by weight loss method. Weight loss study reveals that the formulation consisting of 2 mL of PAE and 25 ppm of Zn 2+ has 98% inhibition efficiency in controlling corrosion of carbon steel immersed in an aqueous solution containing 60 ppm of Cl - . Synergistic parameters suggest that a synergistic effect exists between PAE and Zn 2+ . Polarization study reveals that this system functions as mixed type of inhibitor controlling the cathodic reaction and anodic reaction to an equal extend. AC impedance spectra reveal that a protective film is formed on the metal surface. The FTIR spectra reveal that the protective film consists of Fe 2+ -phyllanthus complex.
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