Cobalt and Molybdate Ions Effects on the Passivation of Iron Based FeCoC Ternary Alloys, in non Deaerated Solution of 10-3 M NaHCO3 + 10-3 M Na2SO4, at 25 °C
Author(s) -
Férid Haddad,
A. Benchettara,
Sif Eddine Amara,
R. Kesri
Publication year - 2007
Publication title -
portugaliae electrochimica acta
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.252
H-Index - 27
eISSN - 1647-1571
pISSN - 0872-1904
DOI - 10.4152/pea.200802181
Subject(s) - molybdate , ternary operation , cobalt , passivation , ion , inorganic chemistry , materials science , metallurgy , chemistry , nuclear chemistry , composite material , computer science , organic chemistry , layer (electronics) , programming language
In the present paper, the electrochemical behaviour of four based iron FeCoC ternary alloys was studied in non deaerated solution of 10 -3 M NaHCO 3 + 10 -3 M Na 2SO 4, at 25 °C, and compared to that of pure iron and cobalt. The inhibition effect of sodium molybdate has also been considered for different concentrations. It was noted that the oxygen oxidizes the FeCoC ternary alloys except that with the most important cobalt content. For this reason, a potentiodynamic polarisation was carried out at different temperatures (25, 35, 45 and 55°C) in which the current growth versus temperature indicates really that molybdate oxidizes this alloy.
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