Removal of Cd(II) Ions from Simulated Wastewater by HCl Modified Cucumis sativus Peel: Equilibrium and Kinetic Study
Author(s) -
Ruchi Pandey,
Nasreen Ghazi Ansari,
Рам Прасад,
Ramesh Murthy
Publication year - 2014
Publication title -
air soil and water research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.409
H-Index - 12
ISSN - 1178-6221
DOI - 10.4137/aswr.s16488
Subject(s) - adsorption , gibbs free energy , endothermic process , chemistry , enthalpy , langmuir adsorption model , aqueous solution , metal ions in aqueous solution , cucumis , monolayer , langmuir , ion , inorganic chemistry , nuclear chemistry , thermodynamics , chromatography , organic chemistry , ecology , biochemistry , physics , biology
This paper describes the adsorption of Cd(II) ions from aqueous solutions by modified Cucumis sativus peel (CSP) by HCl treatment. The optimum pH, adsorbent mass, contact time, and initial ion concentration were determined. The maximum removal efficiency was 84.85% for 20 mg/L Cd(II) ion at pH 5. The adsorption isotherms were obtained using concentrations of the metal ions ranging from 5 to 150 mg/L. The adsorption process follows Langmuir isotherm and pseudo-second-order reaction kinetics. CSPs exhibit monolayer adsorption capacity of 58.14 mg/g at 298 K. The paper also discusses the thermodynamic parameters of the adsorption (the Gibbs free energy, entropy, and enthalpy). Our results establish that the adsorption process was spontaneous and endothermic under normal conditions.
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