Rapid Electrochemical Detection of Radiolysis Products in an Aqueous Solution Exposed to Alpha Particle Beams
Author(s) -
Joseph Edward Liedhegner,
WALTER JENNINGS,
Jesse S. Wainright
Publication year - 2011
Publication title -
international journal of electrochemistry
Language(s) - English
Resource type - Journals
eISSN - 2090-3537
pISSN - 2090-3529
DOI - 10.4061/2011/864126
Subject(s) - radiolysis , aqueous solution , electrochemistry , hydrogen peroxide , alpha particle , yield (engineering) , particle (ecology) , materials science , analytical chemistry (journal) , hydrogen , chemistry , electrode , atomic physics , physics , organic chemistry , oceanography , geology , metallurgy
An electrochemical cell has been developed that allows for the rapid and exhaustive detection of oxygen and/or hydrogen peroxide produced during the radiolysis of aqueous solutions by alpha particle or proton beams. Short, 10–100 s, exposures were sufficient to yield steady-state electrochemical currents proportional to the radiolysis G-factor. The use of thin SiC windows provided a robust means of separating the vacuum environment of the ion-beam accelerator from the aqueous solution at atmospheric pressure with minimal energy loss
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