A Solid Binding Matrix/Mimic Receptor-Based Sensor System for Trace Level Determination of Iron Using Potential Measurements | Zendy

Ayman H. Kamel | Zendy; Felismina T.C. Moreira | Zendy; Tamara Indrusiak | Zendy; M. Goreti F. Sales | Zendy

Open Access

A Solid Binding Matrix/Mimic Receptor-Based Sensor System for Trace Level Determination of Iron Using Potential Measurements

Author(s) -

Ayman H. Kamel,

Felismina T.C. Moreira,

Tamara Indrusiak,

M. Goreti F. Sales

Publication year - 2011

Publication title -

international journal of electrochemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-3537

pISSN - 2090-3529

DOI - 10.4061/2011/643683

Subject(s) - ethylene glycol dimethacrylate , detection limit , potentiometric titration , plasticizer , chemistry , benzoyl peroxide , monomer , phthalate , polyvinyl chloride , polymer chemistry , ethylene glycol , matrix (chemical analysis) , vinyl chloride , ether , molecularly imprinted polymer , polymer , chromatography , selectivity , ion , copolymer , organic chemistry , catalysis , methacrylic acid

Iron(II)-(1,10-phenanthroline) complex imprinted membrane was prepared by ionic imprinting technology. In the first step, Fe(II) established a coordination linkage with 1,10-phenanthroline and functional monomer 2-vinylpyridine (2-VP). Next, the complex was copolymerized with ethylene glycol dimethacrylate (EGDMA) as a crosslinker in the presence of benzoyl peroxide (BPO) as an initiator. Potentiometric chemical sensors were designed by dispersing the iron(II)-imprinted polymer particles in 2-nitrophenyloctyl ether (o-NPOE) plasticizer and then embedded in poly vinyl chloride (PVC) matrix. The sensors showed a Nernstian response for [Fe(phen)3]2+ with limit of detection 3.15 ng mL−1 and a Nernstian slope of 35.7 mV per decade

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research