Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction | Zendy

Milivoj Lovrić | Zendy; Šebojka KomorskyLovrić | Zendy

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Theory of Square-Wave Voltammetry of Two-Step Electrode Reaction Using an Inverse Scan Direction

Author(s) -

Milivoj Lovrić,

Šebojka KomorskyLovrić

Publication year - 2011

Publication title -

international journal of electrochemistry

Language(s) - English

Resource type - Journals

eISSN - 2090-3537

pISSN - 2090-3529

DOI - 10.4061/2011/538341

Subject(s) - square (algebra) , square wave , electrode , horizontal scan rate , inverse , cyclic voltammetry , voltammetry , materials science , chemistry , analytical chemistry (journal) , molecular physics , electrochemistry , physics , mathematics , voltage , quantum mechanics , geometry , organic chemistry

A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed, and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response splits into two peaks if the scan direction is inverted. The separation of these peaks increases with frequency

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