Open AccessFormate Formation and Formate Conversion in Biological Fuels Production
Author(s) -
Bryan R. Crable,
Caroline M. Plugge,
Michael J. McInerney,
Alfons J. M. Stams
Publication year - 2011
Publication title -
enzyme research
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.439
H-Index - 39
eISSN - 2090-0406
pISSN - 2090-0414
DOI - 10.4061/2011/532536
Subject(s) - formate , chemistry , methanol , carbon fixation , biofuel , biohydrogen , fossil fuel , commodity chemicals , carbon fibers , hydrogen , hydrogen production , biochemistry , organic chemistry , catalysis , microbiology and biotechnology , materials science , carbon dioxide , biology , composite number , composite material
Biomethanation is a mature technology for fuel production. Fourth generation biofuels research will focus on sequestering CO2 and providing carbon-neutral or carbon-negative strategies to cope with dwindling fossil fuel supplies and environmental impact. Formate is an important intermediate in the methanogenic breakdown of complex organic material and serves as an important precursor for biological fuels production in the form of methane, hydrogen, and potentially methanol. Formate is produced by either CoA-dependent cleavage of pyruvate or enzymatic reduction of CO2 in an NADH- or ferredoxin-dependent manner. Formate is consumed through oxidation to CO2 and H2 or can be further reduced via the Wood-Ljungdahl pathway for carbon fixation or industrially for the production of methanol. Here, we review the enzymes involved in the interconversion of formate and discuss potential applications for biofuels production
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom