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Surface Characterization of Helium Plasma Treated Nano-SiO2 Sol-gel Coated UHMWPE Filaments by Contact Angle Experiments and ATR-FTIR
Author(s) -
Lijing Wang
Publication year - 2010
Publication title -
journal of fiber bioengineering and informatics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.103
H-Index - 13
eISSN - 2617-8699
pISSN - 1940-8676
DOI - 10.3993/jfbi06201009
Subject(s) - contact angle , materials science , characterization (materials science) , fourier transform infrared spectroscopy , helium , nano , composite material , plasma , chemical engineering , analytical chemistry (journal) , nanotechnology , chemistry , chromatography , organic chemistry , physics , quantum mechanics , engineering
Ultrahigh molecular weight polyethylene (UHMWPE) Filaments has a low surface free energy and therefore modification of their surface properties before any use is often needed. Atmospheric pressure plasmas treatment is a convenient and environment friendly way to obtain these modifications by introducing new chemical groups at the surface without affecting the bulk properties. This paper studies the influence of nano-SiO2 Sol-gel coated pretreatment on atmospheric pressure jet (APPJ) treatment of UHMWPE fibers with helium used as the treatment gas. The surface properties of the plasma-treated UHMWPE Filaments are characterized using contact angle measurements and ATR-FTIR spectroscopy. The UHMWPE Filaments show a remarkable increase in surface free energy after plasma treatment. ATR-FTIR spectroscopy of the plasma-treated UHMWPE Filaments reveals that plasma treatment introduces oxygen-containing functionalities, such as ketones, aldehydes, alcohols and carboxylic acids on the UHMWPE Filaments surface leading to the increase of surface free energy.

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