Open AccessDevelopment of Cyclic Hydrazine and Hydrazide Type Organocatalyst ⎯ Mechanistic Aspects of Cyclic Hydrazine/Hydrazide-Catalyzed Diels-Αlder Reactions
Author(s) -
Ichirō Suzuki,
Ai Hirata,
Kei Takeda
Publication year - 2009
Publication title -
heterocycles
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.242
H-Index - 64
eISSN - 1881-0942
pISSN - 0385-5414
DOI - 10.3987/com-08-s(d)54
Subject(s) - chemistry , hydrazide , hydrazine (antidepressant) , catalysis , organic chemistry , hydrazone , combinatorial chemistry , biochemistry
- Some hydrazines and hydrazides were prepared and screened for their catalytic efficiencies in Diels-Alder reactions. 1 H-NMR studies and ab initio calculations revealed that catalytic efficiencies of these catalysts are greatly dependent on the release of the catalysts from the Diels-Alder adducts.
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