Open AccessPyrene-BODIPY-substituted novel water-soluble cyclotriphosphazenes: synthesis, characterization, and photophysical properties
Author(s) -
Seda Çetindere,
Serkan Yeşi̇lot,
Adem Kılıç
Publication year - 2019
Publication title -
turkish journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.239
H-Index - 46
eISSN - 1303-6130
pISSN - 1300-0527
DOI - 10.3906/kim-1907-40
Subject(s) - chemistry , bodipy , pyrene , fluorescence , fourier transform infrared spectroscopy , photochemistry , fluorescence spectroscopy , spectroscopy , solvent , mass spectrometry , derivative (finance) , boron , organic chemistry , polymer chemistry , chemical engineering , chromatography , engineering , economics , physics , financial economics , quantum mechanics
In the present work, pyrene-boron-dipyrromethene (BODIPY)-substituted novel water-soluble cyclotriphosphazene derivatives (6 and 7) were synthesized by click reactions between a cyclotriphosphazene derivative with a hydrophilic glycol side group (2) and BODIPYs (4 and 5). All of the new compounds (2, 6, and 7) were characterized by Fourier-transform infrared and nuclear magnetic resonance spectroscopy, as well as mass spectrometry and elemental analysis. The photophysical properties of the BODIPY-substituted cyclotriphosphazenes (6 and 7) were investigated by UV-Vis and fluorescence emission spectroscopy in water and water/solvent mixtures. It was found that the target compounds were soluble in water and could be potential candidates as water-soluble fluorescent dyes for the desired applications.
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