Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2',3'-D) pyrrole derivative | Zendy

Arif Kıvrak | Zendy; Hüseyin Bekir Yıldız | Zendy; SELAHATTİN GÖKYER | Zendy; Buket Bezgin Çarbaş | Zendy

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Electrochemical polymerization of a new alkoxy-bridged dithieno (3,2-B:2',3'-D) pyrrole derivative

Author(s) -

Arif Kıvrak,

Hüseyin Bekir Yıldız,

SELAHATTİN GÖKYER,

Buket Bezgin Çarbaş

Publication year - 2018

Publication title -

turkish journal of chemistry

Language(s) - English

Resource type - Journals

eISSN - 1303-6130

pISSN - 1300-0527

DOI - 10.3906/kim-1709-33

Subject(s) - alkoxy group , chemistry , electrochemistry , pyrrole , derivative (finance) , polymerization , polymer , polymer chemistry , organic chemistry , electrode , alkyl , financial economics , economics

A novel alkoxy-bridged dithieno (3, 2-B:2’,3’-D) pyrrole (DTP) derivative was synthesized and its corresponding polymer poly(1,2-bis(2-(4H-dithieno[3,2-b:2’,3’-d]pyrrol-4-yl)ethoxy)ethane) (P(DTP-alkoxy-DTP)) was successfully obtained electrochemically. The effects of alkoxy bridge in the structure on the electrochemical and spectroelectrochemical properties of the polymer were also investigated in detail. The results showed that the polymer film exhibits multielectrochromic behavior and a low band gap of 1.82 eV.

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