Multilayer 3D Chirality and Its Synthetic Assembly | Zendy

Guanzhao Wu | Zendy; Yangxue Liu | Zendy; Zhen Yang | Zendy; Nandakumar Katakam | Zendy; Hossein Rouh | Zendy; Sultan Ahmed | Zendy; Daniel K. Unruh | Zendy; Kazimierz Surowiec | Zendy; Guigen Li | Zendy

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Multilayer 3D Chirality and Its Synthetic Assembly

Author(s) -

Guanzhao Wu,

Yangxue Liu,

Zhen Yang,

Nandakumar Katakam,

Hossein Rouh,

Sultan Ahmed,

Daniel K. Unruh,

Kazimierz Surowiec,

Guigen Li

Publication year - 2019

Publication title -

research

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.8

H-Index - 16

ISSN - 2639-5274

DOI - 10.34133/2019/6717104

Subject(s) - chirality (physics) , enantiomer , axial chirality , absolute configuration , molecule , planar chirality , enantioselective synthesis , materials science , stereochemistry , nanotechnology , crystallography , catalysis , chemistry , organic chemistry , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark

3D chirality of sandwich type of organic molecules has been discovered. The key element of this chirality is characterized by three layers of structures that are arranged nearly in parallel fashion with one on top and one down from the center plane. Individual enantiomers of these molecules have been fully characterized by spectroscopies with their enantiomeric purity measured by chiral HPLC. The absolute configuration was unambiguously assigned by X-ray diffraction analysis. This is the first multilayer 3D chirality reported and is anticipated to lead to a new research area of asymmetric synthesis and catalysis and to have a broad impact on chemical, medicinal, and material sciences in future.

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