Influence of Magnesium Ions in the Seawater Environment on the Improvement of the Corrosion Resistance of Low-Chromium-Alloy Steel
Author(s) -
Sol-Ji Song,
JungGu Kim
Publication year - 2018
Publication title -
materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.682
H-Index - 111
ISSN - 1996-1944
DOI - 10.3390/ma11010162
Subject(s) - seawater , corrosion , materials science , dielectric spectroscopy , metallurgy , alloy , chromium , magnesium alloy , magnesium , artificial seawater , oxide , alloy steel , electrochemistry , chemistry , electrode , oceanography , geology
This study examined the synergic effect of alloying the element Cr and the environmental element Mg 2+ ions on the corrosion property of a low-alloy steel in seawater at 60 °C, by means of electrochemical impedance spectroscopy (EIS), linear polarization resistance (LPR) tests and weight-loss tests. The Mg 2+ ions in seawater played an important role in lowering the electron transfer of the rust layer in the Cr-containing steel. The corrosion resistance of the Cr-containing steel is superior to that of blank steel in Mg 2+ ions containing seawater. XPS and XRD results indicated that the formation of MgFe₂O₄ and a mixed layer (Cr oxide + FeCr₂O₄ + MgCr₂O₄) improved the corrosion resistance of the low-alloy steel in the seawater.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom