1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes | Zendy

Pedro Merino | Zendy; Sonia Anoro | Zendy; F. L. MERCHAN | Zendy; Tomás Tejero | Zendy

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1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes

Author(s) -

Pedro Merino,

Sonia Anoro,

F. L. MERCHAN,

Tomás Tejero

Publication year - 2000

Publication title -

molecules

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.782

H-Index - 149

eISSN - 1433-1373

pISSN - 1420-3049

DOI - 10.3390/50200132

Subject(s) - cycloaddition , chemistry , computational chemistry , 1,3 dipolar cycloaddition , dipole , ab initio , electron , ab initio quantum chemistry methods , nitrone , photochemistry , medicinal chemistry , organic chemistry , molecule , catalysis , physics , quantum mechanics

The 1,3-dipolar cycloaddition reaction of N-benzyl-C-(2-furyl)nitrones with electron-rich alkenes gives preferentially trans-substituted 3,5-disubstituted isoxazolidines (endo approach). These experimental results are in good qualitative agreement with the predicted ones by semiempirical (AM1 and PM3) and ab initio (HF/3-21G) methods

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