Synthesis and Characterization of 2-Butoxyethylxanthate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and their Adducts with Nitrogen Base Ligands | Zendy

Ibraheem A. Al-Qasser | Zendy; Saad E. Al-Mukhtar | Zendy; Nada F. Hana | Zendy

Open Access

Synthesis and Characterization of 2-Butoxyethylxanthate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and their Adducts with Nitrogen Base Ligands

Author(s) -

Ibraheem A. Al-Qasser,

Saad E. Al-Mukhtar,

Nada F. Hana

Publication year - 2014

Publication title -

mağallaẗ ʻulūm al-rāfidayn

Language(s) - English

Resource type - Journals

eISSN - 2664-2786

pISSN - 1608-9391

DOI - 10.33899/rjs.2014.88644

Subject(s) - chemistry , cobalt , ethylenediamine , copper , nickel , zinc , adduct , octahedron , pyridine , metal , octahedral molecular geometry , magnetic moment , inorganic chemistry , xanthate , crystallography , magnetic susceptibility , absorption spectroscopy , medicinal chemistry , crystal structure , organic chemistry , physics , quantum mechanics , condensed matter physics

New complexes and adducts of xanthate of the general formula [M(2-BuoEtxant)2] and [M(2-BuoEtxant)2.nL] Where M= Fe(ΙΙ), Co(ΙΙ), Ni(ΙΙ), Cu(ΙΙ) and Zn(ΙΙ), and (2-BuoEtxant)=2-Butoxyethylxanthate, and n=2 when L= pyridine; Isoquinoline, γ-picoline, 3,5-lutidine, n=1 when L= ethylenediamine, (1,10)-phenanthroline, have been prepared and characterized by metal analyses, infrared, conductance measurements, electronic absorption spectra and susceptibility measurements. Magnetic moment and electronic spectra, indicate that the complexes of type [M(2-BuoEtxant)2] are of tetrahedral geometry while the complexes of type [M(2-BuoEtxant)2.nL] have an octahedral geometry.

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