Synthesis and Characterization of Mn(II), Fe(II) and Co(II) Complexes with 4-Hydroxypiperidinedithiocarbamate and their Adducts with Neutral Bases | Zendy

Hasan A. Mohammed | Zendy; Saad E. Al- Mukhtar | Zendy

Open Access

Synthesis and Characterization of Mn(II), Fe(II) and Co(II) Complexes with 4-Hydroxypiperidinedithiocarbamate and their Adducts with Neutral Bases

Author(s) -

Hasan A. Mohammed,

Saad E. Al- Mukhtar

Publication year - 2014

Publication title -

mağallaẗ ʻulūm al-rāfidayn

Language(s) - English

Resource type - Journals

eISSN - 2664-2786

pISSN - 1608-9391

DOI - 10.33899/rjs.2014.86068

Subject(s) - adduct , chemistry , octahedral molecular geometry , octahedron , triphenylphosphine , tetrahedral molecular geometry , crystallography , metal , magnetic susceptibility , infrared spectroscopy , stereochemistry , crystal structure , organic chemistry , catalysis

A new coordination complexes and adducts of the general formulas [M(hpipdtc)2] and [M(hpipdtc)2Ln] where M= Mn(II), Fe(II), Co (II), (hpipdtc)=4hydroxypiperidinedithiocarbamate, n=1 L= 1, 10phen, en, n=2 L=4-picoline, 3,5-luitidine, triphenylphosphine have been prepared and characterized by metal analyses, infrared, molar conductance measurements, electronic absorption spectra, and susceptibility measurements. Magnetic moments and electronic spectra, suggested tetrahedral geometry for complexes of the type [M(hpipdtc)2] and an octahedral geometry for their base adducts.

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