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Conductometric Studies for Association Reaction of some Amino Acid Complexes in Water
Author(s) -
Yaser O. Al-Allaf,
Mohammad Yahya Al-Tamer,
Marwa N. Abdulfattah
Publication year - 2013
Publication title -
mağallaẗ ʻulūm al-rāfidayn
Language(s) - English
Resource type - Journals
eISSN - 2664-2786
pISSN - 1608-9391
DOI - 10.33899/rjs.2013.80281
Subject(s) - valine , ion association , chemistry , conductivity , molar conductivity , alanine , ion , serine , amino acid , solvent , inorganic chemistry , analytical chemistry (journal) , chromatography , biochemistry , organic chemistry , enzyme
Molar conductivities of dilute solutions for the complexes: Co(II)(alanine + valine), Ni(II)(valine + serine), Ca(II)(alanine + serine), Mg(II)(valine + serine) in water were measured in the temperature range from (293.16–313.16K). The ionic molar conductivity (Λ), the association constant (KA), distance parameter (R), and (σΛ) at best fit values were determined by treating experimental data with Lee-Wheaton conductivity equation. Thermodynamic quantities for the ion association reaction were derived from the temperature dependence of KA. The obtained results provide information on ion – ion and ion-solvent interactions.

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