Synthesis and Characterization of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Hg(II) Complexes with [(N-(N-benzilidin aminoethyl) Iodomethylene Dithiocarbamate] | Zendy

Layla J. Althaher | Zendy

Open Access

Synthesis and Characterization of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Hg(II) Complexes with [(N-(N-benzilidin aminoethyl) Iodomethylene Dithiocarbamate]

Author(s) -

Layla J. Althaher

Publication year - 2013

Publication title -

mağallaẗ ʻulūm al-rāfidayn

Language(s) - English

Resource type - Journals

eISSN - 2664-2786

pISSN - 1608-9391

DOI - 10.33899/rjs.2013.77813

Subject(s) - dithiocarbamate , chemistry , metal , magnetic susceptibility , nickel , transition metal , metal ions in aqueous solution , octahedron , schiff base , zinc , ligand (biochemistry) , octahedral molecular geometry , molar ratio , inorganic chemistry , nuclear chemistry , crystallography , crystal structure , organic chemistry , catalysis , biochemistry , receptor

A new series of transition metal complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Hg(II), with Schiff base (L) (N-(N-benzilidine aminoethyl) iodomethylene dithiocarbamate) is derived from (2aminoethyldithiocarbamato -iodomethane) and benzoyl, by (1:2) metal to ligand molar ratio. The complexes were characterized by metal analysis, magnetic susceptibility, molar conductance and IR, UV-Vis, spectral studies. The data showed that these complexes have the composition of [ML2Cl2] type. The UV-Vis spectral and magnetic susceptibility of the complexes suggest an octahedral geometry around each central metal ion.

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