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Microwave-assisted Degradation of Polyvinyl Chloride Induced by Complexes of Transition Elements
Author(s) -
Tariq Abdul-Jaleel,
Hameed Ali,
Ahmad Obeed
Publication year - 2013
Publication title -
mağallaẗ al-tarbiyaẗ wa-al-ʻilm
Language(s) - English
Resource type - Journals
eISSN - 2664-2530
pISSN - 1812-125X
DOI - 10.33899/edusj.2013.163073
Subject(s) - microwave , polyvinyl chloride , nickel , degradation (telecommunications) , materials science , salt (chemistry) , polyene , chloride , nuclear chemistry , microwave oven , polymer chemistry , chemistry , analytical chemistry (journal) , metallurgy , composite material , organic chemistry , electrical engineering , physics , quantum mechanics , engineering
In this work, the presence of variable metals complex of [N,NBis(Salicylidene)1,2-[diaminoethane] Nickel(II), (Ni-BSEDA). And the PVC film were studied under the microwave radiation. The samples and complex metals salt were prepared using a hand molding casting with percentage ( 0.0 ,0.025 , 0.03, 0.04, 0.05, 0.1 ) % . Degradation studies were carried out using commercial microwave oven at constant power of 400W for all experimental. The specimens were exposed to microwave radiation with multiple time( 0.0 ,15, 30, 60) minutes , A degradation were followed via the decreace in average of molecular weights ( Mw ,Mn ) Tariq Abdul-Jaleel & Hameed Ali & Ahmad Obeed 241 and increase of the growth of absorbency the carbonyl index ICO and polyene index IPO at the total time of 60 minutes .

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