Electrochemistry in Thin Solid Films of Prussian Blue: A Model Demonstration of Reversible Behavior | Zendy

Ryan Hazen | Zendy; Rose M. Spaulding | Zendy; Kasem Kasem | Zendy; Ellen Sigle | Zendy

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Electrochemistry in Thin Solid Films of Prussian Blue: A Model Demonstration of Reversible Behavior

Author(s) -

Ryan Hazen,

Rose M. Spaulding,

Kasem Kasem,

Ellen Sigle

Publication year - 2003

Publication title -

american journal of undergraduate research

Language(s) - English

Resource type - Journals

eISSN - 2375-8732

pISSN - 1536-4585

DOI - 10.33697/ajur.2003.012

Subject(s) - prussian blue , electrochemistry , ion , materials science , redox , metal , electrode , thin film , ion exchange , inorganic chemistry , nanotechnology , chemistry , metallurgy , organic chemistry

This article discusses the effectiveness of Prussian Blue (PB) or KxFeA Y (CN)6]z thin films as a model to demonstrate the concept of reversibility of electron and ion exchange processes. PB structure is modified via exchanging the FeA (the counter ion) with other metal ions that have electrochemically active or inactive redox behavior. The modeling process includes the investigation of the electrochemical behavior of PB before and after modification. The results can be compared and used to derive conclusions about the validity of PB as a model compound.

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