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BINUCLEAR TRANSITION METAL COMPLEXES DERIVED FROM 3, 3’-DIHYDROXY BENZIDIENE AND 2-AMINO THIO PHENOL: SPECTROSCOPIC, THERMOGRAVIMETRIC, DNA CLEAVAGE, AND ANTIMICROBIAL STUDIES
Author(s) -
Kuttiyapillai Sivakumar,
Venkatachalam Chandrasekaran
Publication year - 2020
Publication title -
rasayan journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.281
H-Index - 22
eISSN - 0976-0083
pISSN - 0974-1496
DOI - 10.31788/rjc.2020.1315538
Subject(s) - thermogravimetric analysis , thio , antimicrobial , phenol , chemistry , transition metal , cleavage (geology) , metal , dna , medicinal chemistry , organic chemistry , materials science , biochemistry , catalysis , fracture (geology) , composite material
In this novel paper, we synthesized binuclear complexes of metal chloride of Cu(II), Ni(II) with organic compounds 3,3’-dihydroxy benzidiene and 2-amino thiophenol. The type of complex is [LM2Cl4]. The characterization had been found from elemental analysis, molar conductivity, Infrared, Ultraviolet-visible, cyclic voltammetry, TG-DTA, magnetic measurements, DNA cleavage study and antimicrobial study. The elemental analysis suggested that the metal-ligand ratio is 2:1. The microbes Escherichia coli, Klebsiella pneumonia and Staphylococcus aureus were used to find out antimicrobial activity of binuclear metal complexes.

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