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Vanadyl(II) and Zinc(II) metal complexes with Schiff base 1-propionyl-3-thiosemicarbazide were synthesized and characterized by LCMS, IR, 1 H-NMR (D2O exchangeable), 13 C-NMR, UV-Visible spectra, ESR, TGA, molar conductance and magnetic susceptibility measurements. The spectro-analytical studies revealed the composition as ML for Vanadyl(II) complex and ML2 for Zinc(II) complex. Equilibrium studies revealed that 1-propionyl-3thiosemicarbazide acts as a monobasic ligand by releasing proton from amide and forms 1:1 and 1:2 complex in solution. The cleavage of plasmid pBR322 DNA exhibited hydrolytic cleavage. The compound and its chelates showed antibacterial activity against gram-positive and gram-negative bacteria.

EQUILIBRIUM AND ANTIBACTERIAL STUDIES OF VO(II) AND Zn(II) COMPLEXES WITH 1-PROPIONYL-3- THIOSEMICARBAZIDE