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A set of complexes, [RuCl(CO)(B)(EPh3)L] (where E=P/As; B=PPh3/AsPh3/py; L = ligand), of ruthenium have been synthesized by solution method. The structure of the ruthenium(II) complexes were determined by microanalytical techniques and spectral techniques (CHNS, Infrared, ultraviolet-visible and NMR spectroscopic techniques). FT-IR results reveal that thiosemicarbazone is coordinated to Ru(II)via ONS. In addition, the structure of the compounds, thiosemicarbazone ligand and complexes, was confirmed by Nuclear Magnetic Resonance Spectroscopy. Further, the synthesized ligand and its complexes were analyzed against human pathogens.

SYNTHESIS, CHARACTERIZATION AND CYTOTOXIC ANTIBACTERIAL ACTIVITY OF Ru(II) ETHOXYSALAL THIOSEMICARBAZONE COMPLEXES