SYNTHESIS, CHARACTERIZATION AND CYTOTOXIC ANTIBACTERIAL ACTIVITY OF Ru(II) ETHOXYSALAL THIOSEMICARBAZONE COMPLEXES | Zendy

K. Sampath | Zendy; R. Ashokkumar | Zendy; A. R. Venkatachalam | Zendy; Shanmugaprakash Muthusamy | Zendy

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SYNTHESIS, CHARACTERIZATION AND CYTOTOXIC ANTIBACTERIAL ACTIVITY OF Ru(II) ETHOXYSALAL THIOSEMICARBAZONE COMPLEXES

Author(s) -

K. Sampath,

R. Ashokkumar,

A. R. Venkatachalam,

Shanmugaprakash Muthusamy

Publication year - 2019

Publication title -

rasayan journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.281

H-Index - 22

eISSN - 0976-0083

pISSN - 0974-1496

DOI - 10.31788/rjc.2019.1214099

Subject(s) - semicarbazone , chemistry , antibacterial activity , cytotoxic t cell , combinatorial chemistry , stereochemistry , bacteria , in vitro , biochemistry , biology , genetics

A set of complexes, [RuCl(CO)(B)(EPh3)L] (where E=P/As; B=PPh3/AsPh3/py; L = ligand), of ruthenium have been synthesized by solution method. The structure of the ruthenium(II) complexes were determined by microanalytical techniques and spectral techniques (CHNS, Infrared, ultraviolet-visible and NMR spectroscopic techniques). FT-IR results reveal that thiosemicarbazone is coordinated to Ru(II)via ONS. In addition, the structure of the compounds, thiosemicarbazone ligand and complexes, was confirmed by Nuclear Magnetic Resonance Spectroscopy. Further, the synthesized ligand and its complexes were analyzed against human pathogens.

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