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DENSITY AND ACOUSTIC PROPERTIES OF BINARY LIQUID MIXTURES OF ETHYL ACETOACETATE (EAA) WITH 1- ALKANOLS (C3-C6) AT TEMPERATURE 303.15K
Author(s) -
T. Savitha Jyostna,
G. Ramesh,
D. Sreenu,
B. Satheesh
Publication year - 2018
Publication title -
rasayan journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.281
H-Index - 22
eISSN - 0976-0083
pISSN - 0974-1496
DOI - 10.31788/rjc.2018.1132041
Subject(s) - ethyl acetoacetate , binary number , thermodynamics , materials science , chemistry , chromatography , organic chemistry , mathematics , catalysis , physics , arithmetic
The density and speed of sound of binary liquid mixtures of Ethyl acetoacetate with 1-Propanol, 1-Butanol, 1-Pentanol and 1-Hexanol have been measured over the entire range of composition at 303.15K temperature. From these data, excess thermodynamic parameters namely excess molar volume and deviation in isentropic compressibility have been calculated. The calculated parameters have been fitted to Redlich-Kister type polynomial equation. The values of excess parameters have been explained in terms of molecular interactions that operating between unlike molecules in the binary liquid mixtures of Ethyl acetoacetate with 1-Alkanols.

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