Thermal properties of three dimensional Morse potential for some diatomic molecules via Euler-Maclaurin approximation
Author(s) -
K. Chabi,
Abdelmalek Boumali
Publication year - 2019
Publication title -
revista mexicana de física
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.181
H-Index - 25
eISSN - 2683-2224
pISSN - 0035-001X
DOI - 10.31349/revmexfis.66.110
Subject(s) - diatomic molecule , partition function (quantum field theory) , morse potential , thermal , potential energy , euler's formula , function (biology) , partition (number theory) , physics , molecule , thermodynamics , atomic physics , quantum mechanics , mathematical analysis , mathematics , combinatorics , evolutionary biology , biology
The purpose of this study is to develop a method of calculating the vibration partition function of diatomic molecules for the Morse potential energy. After a brief introduction about the eigensolutions obtained for the problem in question, Via the Euler-Maclaurin formula, we have determined the thermal properties for four diatomics such as \text{H}_{2}, HCl, LiH, and CO. Different situation has been exposed and explained by the appropriate curves of the thermal properties for these diatomics molecules in consideration. In addition, we have shown that our method exposed to calculate these thermal properties can be used to determine these thermodynamic quantities.
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