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Synthesis and crystal structure of the quaternary semiconductor Cu2NiGeS4, a new stannite-type compound
Author(s) -
Gerzón E. Delgado,
And V. Sagredo
Publication year - 2019
Publication title -
revista mexicana de física
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.181
H-Index - 25
eISSN - 2683-2224
pISSN - 0035-001X
DOI - 10.31349/revmexfis.65.355
Subject(s) - tetragonal crystal system , crystal structure , crystallography , valence (chemistry) , rietveld refinement , materials science , adamantane , powder diffraction , semiconductor , chemistry , optoelectronics , organic chemistry
The crystal structure of the quaternary compound Cu 2 NiGeS 4 , belonging to the system I 2 -II-IV-VI 4 , was characterized by Rietveld refinement using X-ray powder diffraction data. This material crystallize with a stannite structure in the tetragonal space group I2m (No 121), Z = 2, unit cell parameters a = 5.3384(1) A, c = 10.5732(3) A, V = 301.32(3) A 3 , acknowledged as a normal valence adamantane-structure.

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