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The isothermal section of the phase diagram of the ternary system Ce–Ti–Sn was constructed in the whol e concentration range at 600°C by means of X-ray powd er diffraction. The binary compounds of the systems Ce–Sn and Ti–Sn dissolve negligible amounts of the third component. Two ternary compounds, CeTi 6Sn4 and ~Ce3TiSn5, were found. The crystal structure of the compound CeTi6Sn4 belongs to the structure type ZrFe6Ge4 (Pearson symbol hR33, space group R-3m, a = 5.8101(11), c = 22.971(5) Å). It completes the row of isotypic RTi 6Sn4 compounds with ZrFe6Ge4-type structure (R = Y, La-Nd, Sm, Gd-Tm, Lu).

Phase equilibria in the ternary system Ce–Ti–Sn at 600°C