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1 Faculty of Physics, Don State Technical University, Gagarin Sq. 1, 344010 Rostov-on-Don, Russian Federation 2 Frantsevych Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, Krzhyzhanovskoho St. 3, 03142 Kyiv, Ukraine 3 Karpenko Physico-Mechanical Institute, National Academy of Sciences of Ukraine, Naukova St. 5, 79601 Lviv, Ukraine * Corresponding author. Tel.: +380-44-4243364, fax: +380-44-4242131; e-mail: khyzhun@ipms.kiev.ua

chemistry of metals and alloys

Electronic properties of Zr4M2O (M = Fe, Co, Ni) intermetallic compounds: first-principles APW+LO calculations and X-ray photoelectron spectroscopy data