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The atomic environment types AETs (coordination pol yhedra) realized in binary and multinary inorganic compounds were analyzed based on a comprehensive se t of literature data. The periodic number PNMD (ordering number listing the chemical elements colu mn by column through the periodic system according to Mendeleyev) was successfully used to classify the A ETs in a generalized (PNMD (central atom) versus PNMD (coordinating atoms) ) – AET matrix. Chemical elements with PNMD > 54 fully control the atomic environment types, regardless of whether they act as central or as coordinating atoms. A generalized AET stability map, using as coordinates PNMD max vs. PNMD min / PNMD max, sub-divides the [central atom–coordinating atoms] combinations so that different atomic environment types occur i n distinct ‘AET class stability domains’. The same matrix (respectively stability map) also shows a clear separation between possible and impossible [central atom-coordinating atoms] combinations . The matrix and stability maps allow, for a chemical element assumed to act as central atom, to predict the most probable AET formed by any coordinating chemical elements, regardless of the stoichiometry and numbe r of chemical elements of the inorganic compound.

Data-driven generalized atomic environment prediction for binary and multinary inorganic compounds using the periodic number