Formation of intermetallic compounds upon cooling of Sn1-xZrx melts | Zendy

S. Mudry | Zendy; Ulrich Klotz | Zendy; A. Korolyshyn | Zendy; I. Shtablavyi | Zendy

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Formation of intermetallic compounds upon cooling of Sn1-xZrx melts

Author(s) -

S. Mudry,

Ulrich Klotz,

A. Korolyshyn,

I. Shtablavyi

Publication year - 2008

Publication title -

chemistry of metals and alloys

Language(s) - English

Resource type - Journals

eISSN - 1998-8087

pISSN - 1998-8079

DOI - 10.30970/cma1.0049

Subject(s) - liquidus , intermetallic , phase diagram , thermodynamics , diffraction , materials science , cooling curve , tin , phase (matter) , eutectic system , crystallization , diagram , x ray crystallography , alloy , crystallography , metallurgy , chemistry , physics , mathematics , statistics , organic chemistry , optics

The structure of Sn1-xZrx (x = 0.02, 0.05, 0.15, 0.25; 0.35; 0.45) alloys has been studied by means of X-ray diffraction methods at different temperatures. The structure factors, pair correlation functions and main parameters have been analyzed. It is shown that the structure of Sn-enriched liquid alloys is inhomogeneous in the region of pre-crystallization temperatures. The solidified phases created upon cooling are in agreement with those present in the equilibrium phase diagram. The X-ray diffraction data were used to determine more exactly the temperatures of the liquidus curve, which is not yet completely investigated.

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