The new structure type Ce5Co4Ge13 | Zendy

B. Belan | Zendy; J. Stepen'-Damm | Zendy; R. Gladyshevskii | Zendy; Oksana Bodak | Zendy

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The new structure type Ce5Co4Ge13

Author(s) -

B. Belan,

J. Stepen'-Damm,

R. Gladyshevskii,

Oksana Bodak

Publication year - 2008

Publication title -

chemistry of metals and alloys

Language(s) - English

Resource type - Journals

eISSN - 1998-8087

pISSN - 1998-8079

DOI - 10.30970/cma1.0035

Subject(s) - orthorhombic crystal system , intermetallic , crystallography , crystal structure , cerium , structure type , type (biology) , materials science , germanium , derivative (finance) , single crystal , cobalt , diffraction , chemistry , metallurgy , alloy , physics , geology , silicon , paleontology , economics , financial economics , optics

The crystal structure of Ce5Co4Ge13 was refined from single-crystal X-ray diffraction data. This new orthorhombic structure type (space group Cmmm, a = 4.265(1), b = 45.175(9), c = 4.293(1) Å) is a filled-up derivative of the Nb5Ga13 type and contains AlB2-, BaNiSn3and AuCu3-type slabs intergrown along [010]. The “interstitial” Co atoms are characterized by bicapped square-antiprismatic [Ce5Ge5] coordination.

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