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Microwave Preparation, Spectral Studies and Antimicrobial Activities Evaluation of Mn(II),Ni(II), Hg(II),Co(II) and Cu(II) Complexes with Schiff Base Ligand
Author(s) -
Rehab Kadem Rahem Al-Shemary
Publication year - 2017
Publication title -
ibn al- haitham journal for pure and applied science
Language(s) - English
Resource type - Journals
eISSN - 2521-3407
pISSN - 1609-4042
DOI - 10.30526/30.3.1602
Subject(s) - ligand (biochemistry) , schiff base , chemistry , chelation , metal , ethylene diamine , nuclear chemistry , inorganic chemistry , medicinal chemistry , stereochemistry , organic chemistry , biochemistry , receptor
New Schiff base and their Mn,Co,Ni, Cu and Hg complexes formed by the condensation of O-phathaldehyde and ethylene diamine (2:1) to give ligand (L 1 ) in the first step ,then the ligand (L 1 ) with 2aminophenol (1:2) to give ligand (L 2 ) were prepared by classic addition through microwave method . These compounds (Ligands and complexes) have been diagnosed electronic spectra, FT-IR, 1 H-& 13 C-NMR (only ligand), magnetic susceptibility, elemental microanalysis and molar conductance measurements. Analytical values displayed that all the complexes appeared (metal: ligand) (1:1) ratio with the six chelation. All the compounds appear a high activity versus four types of bacteria such as; (Escherichia coli), (Staphylococcus aureus),(Bacillus btilis), (Staphylococcus aureus) and (Pseudomonas aeruginosin).

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