Synthesis, characterization and crystal structure determination of new coordination polymers of cadmium (II) based on pyridine hydrazide ligands | Zendy

Behrouz Notash | Zendy

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Synthesis, characterization and crystal structure determination of new coordination polymers of cadmium (II) based on pyridine hydrazide ligands

Author(s) -

Behrouz Notash

Publication year - 2019

Publication title -

iranian journal of crystallography and mineralogy

Language(s) - English

Resource type - Journals

eISSN - 2588-4719

pISSN - 1726-3689

DOI - 10.29252/ijcm.26.4.1001

Subject(s) - hydrazide , pyridine , cadmium , characterization (materials science) , coordination polymer , chemistry , crystal structure , coordination complex , polymer , combinatorial chemistry , polymer chemistry , crystallography , organic chemistry , materials science , nanotechnology , metal

Two new polymeric compounds of cadmium acetate using two isomers of pyridine hydrazide ligands have been synthesized and characterized by X-ray diffraction analysis. Structural analysis shows that both compounds were crystallized in monoclinic crystal system with P21/c space group. Coordination polymer [Cd(OAc)2(L1H)]n (1) which L1H is para pyridine hydrazide, has two dimensional sheets with rectangular net and coordination polymer [Cd2(OAc)3(L2H)L2(EtOH)]n (2) which L2H is meta pyridine hydrazide, has got herringbone structure in 2D dimension.

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