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Synthesis and Characterisation of Hydroxyl-terminated Liquid Natural Rubber by Photo-Fenton Reaction
Author(s) -
Hoai Linh Pham,
B. T.,
Thy San Pham,
Duc Giang Le
Publication year - 2017
Publication title -
asean journal on science and technology for development
Language(s) - English
Resource type - Journals
eISSN - 2224-9028
pISSN - 0217-5460
DOI - 10.29037/ajstd.347
Subject(s) - dept , natural rubber , chemistry , carbon 13 nmr , proton nmr , reaction mechanism , nuclear magnetic resonance spectroscopy , photochemistry , chemical structure , organic chemistry , polymer chemistry , materials science , catalysis , stereochemistry
Hydroxyl-terminated liquid natural rubber (HTNR) was prepared by the photo-Fenton reaction, which was carried out in solution in the presence of H2O2/Fe(II) combined with UV irradiation. The HTNR obtained was characterized by GPC, FT-IR, 1H-NMR, 13C-NMR, DEPT-NMR spectroscopy as well as by chemical methods. A probable mechanism leading to the formation of HTNR was discussed based on the analytical data.

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