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Oxidative Coupling Reactions with Gold
Author(s) -
Hermann A. Wegner
Publication year - 2009
Publication title -
chimia international journal for chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.387
H-Index - 55
eISSN - 2673-2424
pISSN - 0009-4293
DOI - 10.2533/chimia.2009.44
Subject(s) - oxidative phosphorylation , domino , oxidative coupling of methane , coupling (piping) , coupling reaction , chemistry , combinatorial chemistry , transformation (genetics) , catalysis , materials science , organic chemistry , biochemistry , metallurgy , gene
Oxidative coupling reactions are a very powerful tool for the construction of e.g. biaryl compounds, especially because typically no functionalization of the coupling partners is necessary. The use of Au for this transformation is particularly attractive since usually no special precautions to exclude moisture or air are ne- cessary. Furthermore, the combination of oxidative coupling reactions with other Au-catalyzed reactions enables the rapid and efficient construction of molecular complexity, e.g. the constructions of dicoumarins via a domino cyclization oxidative coupling reaction

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