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Ternary rhenium (i) complexes: from fluorescent reporters to interesting scaffolds for dual-imaging heterobimetallic probes
Author(s) -
Louise Marty,
Alison François,
Tetiana Krachko,
Chantal Galaup,
Claude Picard,
Vladimir M. Аmirkhanov,
Éric Benoist
Publication year - 2013
Publication title -
journal of organic and pharmaceutical chemistry
Language(s) - English
Resource type - Journals
eISSN - 2518-1548
pISSN - 2308-8303
DOI - 10.24959/ophcj.13.773
Subject(s) - rhenium , fluorescence , dual (grammatical number) , ternary operation , chemistry , materials science , art , computer science , optics , physics , inorganic chemistry , literature , programming language
Five ternary tricarbonylrhenium(I) complexes based on a pyridinetriazole moiety, so called pyta, were synthesized and spectroscopically characterized. The photophysical properties of these cationic complexes of general formula, [Re(CO)3(pyta-COOMe)L] (L = substituted pyridine derivatives) have been investigated, as well. Three of them are fluorescent and could be considered as interesting scaffolds for the preparation of dual-imaging heterobimetallic species.

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