Synthesis and Characterization of Phthalimide-benzothiazole Mercury(II) Complexes with Diphosphine and Diamines | Zendy

Ahmed A. Irzoqi | Zendy; Ahmed Shaker Marmmus | Zendy; Hayfa Muhammed | Zendy

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Synthesis and Characterization of Phthalimide-benzothiazole Mercury(II) Complexes with Diphosphine and Diamines

Author(s) -

Ahmed A. Irzoqi,

Ahmed Shaker Marmmus,

Hayfa Muhammed

Publication year - 2017

Publication title -

diyala journal for pure science

Language(s) - English

Resource type - Journals

eISSN - 2518-9255

pISSN - 2222-8373

DOI - 10.24237/djps.1301.141c

Subject(s) - benzothiazole , phthalimide , mercury (programming language) , chemistry , characterization (materials science) , medicinal chemistry , combinatorial chemistry , organic chemistry , materials science , nanotechnology , computer science , programming language

Phthalimide-benzothiazole ligand (L) and their complexes of Hg(II) with diphosphine and diamines have been prepared. Conductivity measurements show the 2:1 (ioncomplex ion) behavior of the complexes except for [Hg(L)Cl2] (1) complex which was non-conductive. The Phthalimide-benzothiazole ligand has been observed to be bonded to the Hg(II) ion through the nitrogen and oxygen atoms as a bidentate chelating ligand, whereas the diphosphine and diamine ligands have been bonded as bidentate chelating ligands to give a tetrahedral geometry around the Hg(II) ion.

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