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Sintering of Cr, Mn and Si bearing steels has recently attracted both   experimental and theoretical attention and processing in semiclosed   containers has been reproposed. This paper brings together relevant   thermodynamic data and considers the kinetics of some relevant chemical   reactions. These involve iron and carbon, water vapour, carbon monoxide and   dioxide, hydrogen and nitrogen of the sintering atmospheres and the alloying   elements Cr, Mn, Mo and Si. The paper concludes by presenting mechanical   properties data for three steels sintered in local microatmosphere with   nitrogen, hydrogen, nitrogen-5% hydrogen and air as the furnace gas

Chemical reactions during sintering of Fe-Cr-Mn-Si-Ni-Mo-C-steels with special reference to processing in semi-closed containers