Isokinetic parameters of thermal degradation of powder of [Cd(N-Boc-gly)2(H2O)2]n | Zendy

Nebojša Begović | Zendy; Milica M. Vasić | Zendy; A. Grkovic | Zendy; Vladimir Blagojević | Zendy; Dragica M. Minić | Zendy

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Isokinetic parameters of thermal degradation of powder of [Cd(N-Boc-gly)2(H2O)2]n

Author(s) -

Nebojša Begović,

Milica M. Vasić,

A. Grkovic,

Vladimir Blagojević,

Dragica M. Minić

Publication year - 2014

Publication title -

science of sintering

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.309

H-Index - 25

eISSN - 1820-7413

pISSN - 0350-820X

DOI - 10.2298/sos1403323b

Subject(s) - degradation (telecommunications) , covalent bond , ligand (biochemistry) , polymer , kinetic energy , coordination polymer , materials science , dehydration , crystallography , chemistry , organic chemistry , telecommunications , biochemistry , physics , receptor , quantum mechanics , computer science

The coordination polymer [Cd(N-Boc-gly)2(H2O)2]n undergoes thermally induced degradation in temperature region between 60 and 900oC. Kinetic parameters were determined for dehydration (63-123oC) and further degradation processes (123-461°C) using different isoconversional and non-isoconversional methods. Due to appearance of kinetic “compensation effect”, isokinetic temperatures were determined for individual degradation processes and correlated with resonant vibrational frequencies ascribed to Cd-OH2 coordination bond, Cd-O (O from N-Boc-glyH ligand) coordination bond and C-O covalent bond. [Projekat Ministarstva nauke Republike Srbije, br. 172015

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