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Development of new material for the environmental-friendly energy generation processes
Author(s) -
Svetlana Ristić,
Ana Jovićević,
Stefan Kocić,
M. Spasojević,
A. Maričić
Publication year - 2011
Publication title -
science of sintering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.309
H-Index - 25
eISSN - 1820-7413
pISSN - 0350-820X
DOI - 10.2298/sos1101071r
Subject(s) - cobalt , palladium , hydrogen , hydrogen storage , materials science , catalysis , desorption , dissociation (chemistry) , absorption (acoustics) , cryo adsorption , differential scanning calorimetry , adsorption , molecule , isothermal process , chemical engineering , inorganic chemistry , chemistry , organic chemistry , metallurgy , composite material , physics , engineering , thermodynamics
The aim of this study was to develop a new material which has high hydrogen storage capacity and hydrogen absorption/desorption rate. This material, which is based on cobalt powder onto which palladium was chemically deposited can be used in environmentally friendly energy generation processes, thus ensuring preventive protection of human health. Hydrogen absorption was investigated using differential scanning calorimetry (DSC) and by measuring hydrogen pressure under isothermal and non-isothermal conditions in a chamber containing either pure cobalt powder either cobalt powder onto which palladium was chemically deposited (Co-0.003 Pd). The mechanism of hydrogen absorption has been described. It was noticed that palladium catalyses hydrogen absorption by dissociating the adsorbed H2 molecules into H atoms more rapidly on its own atoms than on cobalt ones. The catalysis of dissociation of H2 molecules enabled hydrogen absorption into Co-0.003 Pd powder to occur at lower temperatures. The results of this study enable integration of technological and public health investigation in order to ensure preventive protection of human health through enviromental protection

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