On the application of Laplace pressure in the science of sintering
Author(s) -
A.F. Lisovsky
Publication year - 2010
Publication title -
science of sintering
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.309
H-Index - 25
eISSN - 1820-7413
pISSN - 0350-820X
DOI - 10.2298/sos1003357l
Subject(s) - laplace transform , laplace pressure , curvature , expression (computer science) , constant (computer programming) , laplace's equation , surface (topology) , mathematical analysis , mathematics , thermodynamics , geometry , physics , partial differential equation , computer science , surface tension , programming language
An equation of the Laplace pressure derived using the Gibbs thermodynamic method have been discussed and the correct applications of the equation have been substantiated. It has been shown that the expression is applicable only to macrovolumes for the description of surfaces with a constant curvature, but not to the description of nanodisperced systems and surfaces with variable curvature. The expression of the Laplace pressure applicable to a crystal and the cavity limited by a surface of any geometrical shape have been derived
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