Characterization and properties of barium bismuth titanate
Author(s) -
J.D. Bobić,
Mirjana Vijatovic,
Tadej Rojac,
B.D. Stojanović
Publication year - 2009
Publication title -
processing and application of ceramics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.326
H-Index - 15
eISSN - 2406-1034
pISSN - 1820-6131
DOI - 10.2298/pac0902009b
Subject(s) - materials science , calcination , barium titanate , microstructure , ball mill , bismuth titanate , scanning electron microscope , bismuth , dielectric , stoichiometry , ceramic , chemical engineering , characterization (materials science) , sintering , mineralogy , composite material , ferroelectricity , nanotechnology , metallurgy , chemistry , biochemistry , optoelectronics , engineering , catalysis
BaBi 4 Ti 4 O 15 (BBiT) was prepared from stoichiometric amounts of BaTiO 3 (BT) and Bi 4 Ti 3 O 12 (BIT) obtained via mechanochemical synthesis. Mechanochemical synthesis was performed in air atmosphere in a planetary ball mill. BBiT ceramics were sintered at 1100°C, 1110°C and 1120°C for 1 h without pre-calcination step. The formation of phase and crystal structure of BT, BIT and BBiT were verified using X-ray analysis. The morphol- ogy of obtained powders and microstructure were examined using scanning electron microscopy. The electri- cal properties of sintered samples were carried out and BBiT shows behaviour typical for relaxor ferroelectrics and dielectric constant at room temperature is approximately 93.
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